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Kinetic Regularities of Oligomerization of Decene-1 in the Presence of the Ionic Liquid of Chloraluminate Type
Current Issue
Volume 1, 2014
Issue 3 (August)
Pages: 18-23   |   Vol. 1, No. 3, August 2014   |   Follow on         
Paper in PDF Downloads: 30   Since Aug. 28, 2015 Views: 1319   Since Aug. 28, 2015
Authors
[1]
Akif Hamid Azizov, The Institute of Petrochemical Processes Named after Acad. Y. H. Mammedaliyev of Azerbaijan National Academy of Sciences Baku branch of Moscow State University after M. V. Lomonosov.
[2]
Reyhan Valy Aliyeva, The Institute of Petrochemical Processes Named after Acad. Y. H. Mammedaliyev of Azerbaijan National Academy of Sciences Baku branch of Moscow State University after M. V. Lomonosov.
[3]
Khayala Haydar Seidova, The Institute of Petrochemical Processes Named after Acad. Y. H. Mammedaliyev of Azerbaijan National Academy of Sciences Baku branch of Moscow State University after M. V. Lomonosov.
[4]
Rasim Pasha Jafarov, The Institute of Petrochemical Processes Named after Acad. Y. H. Mammedaliyev of Azerbaijan National Academy of Sciences Baku branch of Moscow State University after M. V. Lomonosov.
[5]
Igrar Geyrat Nazarov, The Institute of Petrochemical Processes Named after Acad. Y. H. Mammedaliyev of Azerbaijan National Academy of Sciences Baku branch of Moscow State University after M. V. Lomonosov.
[6]
Bahiya Rahib Mextiyeva, The Institute of Petrochemical Processes Named after Acad. Y. H. Mammedaliyev of Azerbaijan National Academy of Sciences Baku branch of Moscow State University after M. V. Lomonosov.
Abstract
The oligomerization of decene-1 in various conditions in the presence of the ionic liquid of chloroaluminate type has been carried out, the kinetic curves have been constructed, the experimental and theoretical rate constants have been determined, the order of oligomerization process on monomer and catalyst has been established.
Keywords
Oligomerization, Ionic Liquids, Decene-1, Kinetic Regularities, -Olefins, PAO
Reference
[1]
Wasserscheid, P. & Welton, T. (2003) “Ionic Liquids in Synthesis”, Wiley-VCH, Weinheim,
[2]
Alexander Kokorin (2011) “Ionic liquids: applications and perspectives”, P. 686
[3]
Xanmetov A. A., Asgerova Kh.H., Aliyeva R.V., Azizov A.H., (2010) “Ionic liquids in the oligomerization and polymerization processes of olefins” Processes of Petrochemistry and oil refining,, №4, pp. 309-328
[4]
Azizov A.H., Aliyeva R.V., E.S. Kalbaliyeva., Ibrahimova M.J. (2010), “Selective synthesis and mechanism of formation of oligoalkylnaphetic oils by oligo cyclization of 1-hexene the presence of ionic liquids catalyst” // Applied Catalysis A: General Volume 375, Issue 1, pp. 70–77
[5]
Azizov A.H., Aliyeva R.V., Seidova Kh.H. (2013), “Oligoalkylnaphtenic (C6-C12) oils obtained in the presence of Ti-containing ionic-liquid catalysts” //Green and Suitable Chemistry, №3, pp. 18-26
[6]
Azizov A.H., Aliyeva R.V., Asgerova Kh.H. (2013) “Synthesis and properties of oligoalkylnaphtenic synthetic oils in the presence of ionic-liquid catalyst” // 5th congress of ionic liquids, Algarve, Portugal, pp 21-25
[7]
James E. House (2007) “Principles of chemical kinetics” Elsevier Inc, P. 320
[8]
Abilov A. Q., Veliyeva F. M., Aliyev F.T. (1987) “Packages of the applied programs” Evaluation of kinetic parameters of multipath stationary catalytic reactions, QOSFAP SSSR , registration № 50880300906
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