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Synthesis and Reactivity of Tetrakis Oxirane (Ylmehtyl) BisPhenyl Carbonodihydrazide (TOY-BPCH) Compound
Current Issue
Volume 4, 2017
Issue 3 (June)
Pages: 18-25   |   Vol. 4, No. 3, June 2017   |   Follow on         
Paper in PDF Downloads: 36   Since Nov. 23, 2017 Views: 1040   Since Nov. 23, 2017
Authors
[1]
Muhammad Rizwan, Department of Chemistry, University of Engineering & Technology, Lahore, Pakistan.
[2]
Sobia Naseem, Department of Chemistry, University of Engineering & Technology, Lahore, Pakistan.
Abstract
Catalyst Free based synthesis of Tetrakis Oxirane (Ylmehtyl) BisPhenyl Carbonodihydrazide with Multi- reactive group of Epoxides has been developed based on a sharpless Sym. Diphenylcarbazide in combination of hot Ethanol and Epichlorohydrin. A three component cycloaddition of a 1, 5 diphenyl carbazide, hot ethanol and epichlorohydrin to form a highly functionalized Tetrakis hydroxy chloro diphenyl carbazide (THCDPC) serves as the foundation for the synthesis of Tetrakis Oxiranes (ylmethyl) bisphenyl carbonodihydrazide (TOY-BPCH). The resulting product is followed by the neutralization with NaOH. Employing this approach the hydrophobic neutral based multi-reactive group of oxiranes bisphenyl carbonodihydrazide was synthesized in two steps and shown it 80% yield. The structure of the newly synthesized compound was characterized on the basis of FTIR, ¹H-NMR and LC-MS spectral data.
Keywords
1, 5-diphenylcarbazide, Epichlorohydrin, Hot Ethanol, Sod Hydroxide
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