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Treatment of Spent Caustic from Ethylene Plant Using Electro-Fenton Technique
Current Issue
Volume 2, 2015
Issue 4 (July)
Pages: 37-46   |   Vol. 2, No. 4, July 2015   |   Follow on         
Paper in PDF Downloads: 77   Since Aug. 28, 2015 Views: 1198   Since Aug. 28, 2015
Authors
[1]
A. Gameel, Chemical Engineering Department, Alexandria University, Alexandria, Egypt.
[2]
G. Malash, Chemical Engineering Department, Alexandria University, Alexandria, Egypt.
[3]
A. A. Mubarak, Chemical Engineering Department, Alexandria University, Alexandria, Egypt.
[4]
M. Hussein, Chemical Engineering Department, Alexandria University, Alexandria, Egypt.
Abstract
The treatment of sulfidic spent caustic produced from ethylene plant by electro fenton technique using iron and stainless steel electrodes was investigated. The effect of operating conditions such as current density, H2O2 concentration, reaction time, initial pH and H2O2 feeding mode on the efficiency of electro fenton method was studied. The results show that maximum COD removal of 83.4% was achieved at current density = 3.3 mA/cm2, H2O2 concentration = 1875 mg H2O2/L and initial pH=3. Multi steps and continuous addition mode were employed; it was found that a highest COD removal achieved 89.7% at continuous addition of H2O2. It is demonstrated that electro fenton method can effectively treat spent caustic.
Keywords
Spent Caustic, Electro-Fenton, Wastewater Treatment, COD Removal
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