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Adsorption Potential of Gliricidia sepium on Disperse Yellow 211 Dye
Current Issue
Volume 5, 2018
Issue 3 (September)
Pages: 40-52   |   Vol. 5, No. 3, September 2018   |   Follow on         
Paper in PDF Downloads: 44   Since Jul. 2, 2018 Views: 1027   Since Jul. 2, 2018
Authors
[1]
Abe Taiwo Oluwasola, Department of Chemistry, Federal University of Technology, Akure, Nigeria.
[2]
Lajide Labunmi, Department of Chemistry, Federal University of Technology, Akure, Nigeria.
[3]
Owolabi Bodunde Joseph, Department of Chemistry, Federal University of Technology, Akure, Nigeria.
[4]
Adebayo Albert Ojo, Department of Chemistry, Federal University of Technology, Akure, Nigeria.
[5]
Ayodele Olajide, Department of Chemistry, Ekiti State University, Ado Ekiti, Nigeria.
Abstract
Gliricidia sepium and Gliricidia sepium Cellulose were used for the removal of disperse yellow 211 dye from aqueous solutions. The adsorbents were characterized using different instrumental analyses, and thereafter subjected to batch adsorption process. The adsorbents physical properties are similar in density, Gliricidia sepium has higher ash and silica contents compared with Gliricidia sepium cellulose. The Fourier Transform Infrared Spectroscopy (FTIR) revealed the functional groups present, while Scanning Electron Microscopy (SEM) analysis revealed changes inherent by the removal of lignin and hemicellulose from Gliricidia sepium to obtain Gliricidia sepium cellulose. Point zero charge for Gliricidia sepium biomass and Gliricidia sepium cellulose were observed at pH 4.2 and 6.0 respectively. The quantity of disperse yellow 211 dye adsorbed was strongly dependent on pH and temperature. The adsorption system using Gliricidia sepium and its cellulose were best described by pseudo-second order kinetic model with correlation coefficient (R2) of 0.945 and 0.997, respectively. Based on the high correlation coefficient, adsorption using Gliricidia sepium obeyed Langmuir isotherm while Gliricidia sepium cellulose followed Freundlich isotherm. The underutilized Gliricidia sepium in its crude form and as cellulose has proven to be a good adsorbent for the removal of dispersed yellow 211 dye.
Keywords
Gliricidia sepium, Disperse Yellow 211 Dye, Adsorbents, Cellulose, Kinetics, Biomass
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